WebJul 18, 2016 · Abstract. We examine anharmonic contributions to the optical phonon frequency in bulk Td-MoTe2 phase through temperature-dependent Raman spectroscopy. At temperatures greater than 100 K we find that the optical phonon modes redshift linearly with temperature in agreement with the Gruneisen model. Below 100 K the phonon frequency … WebNov 1, 2024 · Anharmonicity is an essential property of two-dimensional materials due to its significant impact on lattice dynamics – involving interactions between phonons, thermal expansion of the structure, and interaction with the substrate. The effects manifest in temperature-dependent redshifts of the phonon frequencies and reduced lifetime.
(PDF) Record-Low and Anisotropic Thermal Conductivity of Quasi-1D Bulk
WebApr 12, 2024 · Metavalent bonding has attracted immense interest owing to its capacity to impart a distinct property portfolio to materials for advanced functionality. Coupling metavalent bonding to lone pair expression can be an innovative way to propagate lattice anharmonicity from lone pair-induced local symmetry-breaking via the soft p-bonding … WebIn addition, the performance of the phonon group velocity, phonon anharmonicity, and scattering channel shows that the ultra-low k l of the novel 2D TlInSe 3 is attributed to the stronger phonon anharmonicity, lower phonon group velocity, and the scattering interaction of ZA + O→O, TA + O→O, and LA + O→O process. In addition, the weak Tl ... the pentecostals of michigan city
Polycrystalline ZrTe5 Parametrized as a Narrow-Band-Gap …
WebJul 18, 2016 · Abstract. We examine anharmonic contributions to the optical phonon frequency in bulk Td-MoTe2 phase through temperature-dependent Raman spectroscopy. … WebApr 12, 2024 · Raman spectra arise from the inelastic scattering of photons with phonons. The lattice strain developed in the material, the quantum size effect, bond strength, phonon decay, and electron–phonon coupling strength can be characterized by analyzing the shift in peak position and FWHM of Raman spectra. 1–5 1. P. M. WebOct 5, 2024 · Temperature-dependent vibrational modes of bulk ZrTe 5 crystals have been quantified in order to study the phonon anharmonicity. The temperature range is … sian ritchie wsu